THE SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURES OF BIMETALLIC ETHOXIDES OF BARIUM AND TITANIUM, AND CALCIUM AND TITANIUM - [M(TI-2(MU(3)-OET)(2)(MU-OET)(3)(OET)(4))(2)] (M=CA, BA)

Authors
TUREVSKAYA EP KESSLER VG TUROVA NY PISAREVSKY AP YANOVSKY AI STRUCHKOV YT
Citation
Ep. Turevskaya et al., THE SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURES OF BIMETALLIC ETHOXIDES OF BARIUM AND TITANIUM, AND CALCIUM AND TITANIUM - [M(TI-2(MU(3)-OET)(2)(MU-OET)(3)(OET)(4))(2)] (M=CA, BA), Journal of the Chemical Society, Chemical Communications, (19), 1994, pp. 2303-2304
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
19
Year of publication
1994
Pages
2303 - 2304
Database
ISI
SICI code
0022-4936(1994):19<2303:TSCAMO>2.0.ZU;2-E
Abstract
The X-ray single-crystal studies of [M{Ti-2(OR)(9)}(2)] (M = Ca, Ba; R = Et) obtained from-EtOH solutions in 1:4 metal-titanium ratios show that these complexes, both in the-solid state and in solution, are com posed of symmetric molecules, in which the central eight-coordinated m etal atom is bound to two face-sharing bioctahedral [Ti-2(OR)(9)] grou ps.