St. Lin et Rm. German, INTERACTION BETWEEN BINDER AND POWDER IN INJECTION-MOLDING OF ALUMINA, Journal of Materials Science, 29(19), 1994, pp. 5207-5212
In injection moulding of alumina the binder components interacted with
the alumina powder by a Lewis acid-base reaction. Among the binder co
mponents used, stearic acid played a major role in determining the pro
cess behaviour even though its composition was only 4 wt% of the total
binder (1.8 vol% of the formulation including powder). The effects of
the chemisorbed stearic acid due to the Lewis acid-base interaction w
ere a reduction of the apparent viscosity by a factor of 20, minimized
separation of binder from the powder during moulding, but a higher co
ntent of binder burnout residue than in the carbonyl-iron system.