We developed an emitter diffusion process that yields a near-ideal dop
ing profile with a passivating oxide in a single furnace step. Because
this process subjects the material to only one high-temperature therm
al excursion, bulk lifetime is better preserved. This is especially tr
ue for lower-cost silicon materials containing a high concentration of
oxygen or carbon. Using this process, we routinely obtain one-sun cel
l efficiencies over 19% on float-zone material and over 18% on Czochra
lski material. Using solar-grade Czochralski material, we have demonst
rated record efficiencies of 18.3% at one sun and 20.0% under concentr
ation. Simple processes that yield high-performance diffusion profiles
are expected to become increasingly important as manufacturers adopt
improved techniques for ohmic contacts.