H. Herremans et W. Grevendonk, COMPARISON OF STEADY-STATE OPTICAL MODULATION SPECTRA OF B2H6-DOPED AND B(CH3)(3)-DOPED A-SI(-C)-H FILMS, Journal of non-crystalline solids, 210(2-3), 1997, pp. 204-208
A series of diborane-doped hydrogenated amorphous silicon films and a
series of trimethylboron-doped hydrogenated amorphous silicon-carbon a
lloys have been studied by means of steady-state optical modulation sp
ectroscopy (OMS) at room temperature and at a temperature of 20 K. For
both materials, the differences between doped and undoped films can b
e associated with the dopant states. A comparison of the spectra of fi
lms with different doping gases leads to the observation that the trim
ethylboron-doped samples show a strong bleaching at low temperature, c
ausing a sign reversal of the ORIS signal; this effect is ascribed to
the broader band tails due to the incorporation of carbon in the films
.