OXYFLUORINATED MICROPOROUS COMPOUNDS .11. SYNTHESIS AND CRYSTAL-STRUCTURE OF ULM-10 - THE 1ST BIDIMENSIONAL MIXED-VALENCE IRON FLUOROPHOSPHATE WITH INTERCALATED ETHYLENEDIAMINE

Authors
CAVELLEC M RIOU D FEREY G
Citation
M. Cavellec et al., OXYFLUORINATED MICROPOROUS COMPOUNDS .11. SYNTHESIS AND CRYSTAL-STRUCTURE OF ULM-10 - THE 1ST BIDIMENSIONAL MIXED-VALENCE IRON FLUOROPHOSPHATE WITH INTERCALATED ETHYLENEDIAMINE, Journal of solid state chemistry, 112(2), 1994, pp. 441-442
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
112
Issue
2
Year of publication
1994
Pages
441 - 442
Database
ISI
SICI code
0022-4596(1994)112:2<441:OMC.SA>2.0.ZU;2-A
Abstract
The first oxyfluorinated iron(II, III) phosphate (Fe3+Fe2+F2 (HPO4)2(H 2O)2, ethylenediamine] with an open structure has been synthesized. It is triclinic (P-1 (No. 2), a = 5.174(2) angstrom, b = 7.518(2) angstr om, c = 8.773(3) angstrom, alpha = 108.37(1)-degrees, beta = 97.33(2)- degrees, gamma = 109.86(2)-degrees, Z = 1). Its bidimensional structur e contains chains of Fe(II) and Fe(III) octahedra, arranged in an orde red way and linked to each other by phosphate groUpS. (C) 1994 Academi c Press, Inc.