Kl. Ngai et al., THEORETICAL BASIS AND GENERAL APPLICABILITY OF THE COUPLING MODEL TO RELAXATIONS IN COUPLED SYSTEMS, Journal of alloys and compounds, 212, 1994, pp. 327-332
The coupling model proposed more than a decade ago for the description
of relaxations in complex correlated systems by one of us (KLN) have
been shown repeatedly to be applicable to amorphous polymers, viscous
liquids, the glassy state, metallic glasses, glassy ionic conductors a
nd etc. In these examples, the relaxing species are dense packed and m
utually interacting. As a consequence, the constraints between them ha
ve a strong influence on the relaxation dynamics. Very recent quasiela
stic neutron scattering experimental data as well as molecular dynamic
s simulation results which provide dramatic proof of the validity of t
he coupling model will be discussed. The applicability of the coupling
model to some relaxations in metals including precipitates and the Sn
oek-Koster relaxation is less obvious but has recently been proposed,
justified and demonstrated to be relevant by one of us (YNW). The appl
icability of the coupling model to these and other problems of immedia
te interest to participants of ICIFUAS-10 will be summarized and discu
ssed. For Snoek-Koster relaxation, additional experimental data in ult
ra-high purity iron containing low concentration of carbon obtained by
one of us (LBM) show characteristics that cannot be explained by Seeg
er's model of thermally activated formation of kink pairs on screw dis
locations in the presence of foreign interstitial atoms, but are consi
stent with the coupling model.