INVESTIGATION OF THE GROWTH OF CO ON CU(111) AND SB CU(111) USING PHOTOELECTRON FORWARD SCATTERING/

Citation
V. Scheuch et al., INVESTIGATION OF THE GROWTH OF CO ON CU(111) AND SB CU(111) USING PHOTOELECTRON FORWARD SCATTERING/, Surface science, 318(1-2), 1994, pp. 115-128
Citations number
40
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00396028
Volume
318
Issue
1-2
Year of publication
1994
Pages
115 - 128
Database
ISI
SICI code
0039-6028(1994)318:1-2<115:IOTGOC>2.0.ZU;2-K
Abstract
We recorded the angular anisotropies of photoelectron intensities aris ing from thin Co layers on a clean and Sb-covered Cu(111) surface. For ward scattering leads to intensity enhancements along close-packed dir ections and thus, the azimuthal distributions reveal information about the mode of heteroepitaxial growth. For Co on the clean Cu surface we find evidence for the formation of three-dimensional islands even at low Co coverages. At about a nominal coverage of 4 ML, the Co layer un dergoes a structural transition from fee to hcp stacking which can be easily identified by means of symmetry of the angular distributions. T he influence of Sb as a surfactant on the growth behaviour has also be en studied. Showing the typical effect of segregating to the surface, Sb induces the Co film to grow in a rather flat manner. Accordingly, t he fcc --> hcp transition is delayed to a nominal Co coverage beyond 1 0 ML.