V. Scheuch et al., INVESTIGATION OF THE GROWTH OF CO ON CU(111) AND SB CU(111) USING PHOTOELECTRON FORWARD SCATTERING/, Surface science, 318(1-2), 1994, pp. 115-128
We recorded the angular anisotropies of photoelectron intensities aris
ing from thin Co layers on a clean and Sb-covered Cu(111) surface. For
ward scattering leads to intensity enhancements along close-packed dir
ections and thus, the azimuthal distributions reveal information about
the mode of heteroepitaxial growth. For Co on the clean Cu surface we
find evidence for the formation of three-dimensional islands even at
low Co coverages. At about a nominal coverage of 4 ML, the Co layer un
dergoes a structural transition from fee to hcp stacking which can be
easily identified by means of symmetry of the angular distributions. T
he influence of Sb as a surfactant on the growth behaviour has also be
en studied. Showing the typical effect of segregating to the surface,
Sb induces the Co film to grow in a rather flat manner. Accordingly, t
he fcc --> hcp transition is delayed to a nominal Co coverage beyond 1
0 ML.