The first steps of the formation of the nickel-alumina interface were
characterized by Auger electron spectroscopy, X-ray photoelectron spec
troscopy and by Auger parameter (alpha') analysis. gamma-alumina thin
films were used as support to avoid static charge problems which occur
on bulk surfaces. The electronic structure of the interface yields ev
idence for the formation of oxide phases which give an ionic character
to the nickel-alumina bonding.