TRAKIS(TETRAKIS)2-PROPANOLATO)TITANIUM]TETRABARIUM

Citation
B. Gaskins et al., TRAKIS(TETRAKIS)2-PROPANOLATO)TITANIUM]TETRABARIUM, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1387-1390
Citations number
5
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
9
Pages
1387 - 1390
Database
ISI
SICI code
0108-2701(1994)50:<1387:T>2.0.ZU;2-2
Abstract
The title compound, [Ba4{mu3-OTi(C3H7O)4}4(C3H7OH)3], is a BaTiO3 mole cular precursor. The structure is based on a Ba4 tetrahedral cluster w ith all faces capped by OTi(O(i)Pr)4 groups. Two of the faces are symm etrically capped (three mu2-O atoms) and two are unsymmetrically cappe d (two mu2-O atoms and one mu3-O atom).