A (PHENYLDITHIOCARBAMATO)RHODATELLURABORANE COMPOUND - -(ETA(2)-S2CN(H)PH)-2-(PPH3)-CLOSO-2,1-RHTEB10H10]

Authors
FERGUSON G OCONNELL D SPALDING TR
Citation
G. Ferguson et al., A (PHENYLDITHIOCARBAMATO)RHODATELLURABORANE COMPOUND - -(ETA(2)-S2CN(H)PH)-2-(PPH3)-CLOSO-2,1-RHTEB10H10], Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1432-1434
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
9
Pages
1432 - 1434
Database
ISI
SICI code
0108-2701(1994)50:<1432:A(C-->2.0.ZU;2-8
Abstract
The Rh atom in 2-(N-phenyldithiocarbamato-S,S')-2 phosphine)-closo-2,1 -rhodatelluradodecaborane(12), [Rh(C7H6NS2)(C18H15P)(B10H10Te)], is bo nded to triphenylphosphine [Rh-P 2.4020 (5) angstrom], N-phenyldithioc arbamate [Rh-S 2.4132(5) and 2.3577(6) angstrom] and the TeB4 face of the TeB10H10 ligand [Rh-Te 2.5812 (3) angstrom].