RATIONAL DESIGN OF MN-SALEN CATALYST (2) - HIGHLY ENANTIOSELECTIVE EPOXIDATION OF CONJUGATED CIS-OLEFINS

Authors
SASAKI H IRIE R HAMADA T SUZUKI K KATSUKI T
Citation
H. Sasaki et al., RATIONAL DESIGN OF MN-SALEN CATALYST (2) - HIGHLY ENANTIOSELECTIVE EPOXIDATION OF CONJUGATED CIS-OLEFINS, Tetrahedron, 50(41), 1994, pp. 11827-11838
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
41
Year of publication
1994
Pages
11827 - 11838
Database
ISI
SICI code
0040-4020(1994)50:41<11827:RDOMC(>2.0.ZU;2-I
Abstract
On the basis of the newly proposed hypothesis on the mechanism of asym metric induction, highly efficient (salen)managanese(III) complex (3) was constructed as a catalyst for asymmetric epoxidation. With this ca talyst, the highest level of enantioselectivity was realized in the ep oxidation of various conjugated cis-olefins.