BIS(ETA(5)-PENTAMETHYLCYCLOPENTADIENYL)-PLATINUM AND (ETA(5)-CYCLOPENTADIENYL) (ETA(5)-PENTAMETHYLCYCLOPENTADIENYL)-PLATINIUM DICATIONS .4.METALLOCENES

Authors
GUSEV OV PEGANOVA TA PETERLEITNER MG PEREGUDOVA SM DENISOVICH LI USTYNYUK NA MAITLIS PM
Citation
Ov. Gusev et al., BIS(ETA(5)-PENTAMETHYLCYCLOPENTADIENYL)-PLATINUM AND (ETA(5)-CYCLOPENTADIENYL) (ETA(5)-PENTAMETHYLCYCLOPENTADIENYL)-PLATINIUM DICATIONS .4.METALLOCENES, Journal of organometallic chemistry, 480(1-2), 1994, pp. 30000016-30000017
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
480
Issue
1-2
Year of publication
1994
Pages
30000016 - 30000017
Database
ISI
SICI code
0022-328X(1994)480:1-2<30000016:BA(>2.0.ZU;2-U
Abstract
Reaction of [Pt2(eta5-C5Me5)2(mu-Br)3]3+ (Br-)3 with C5R5H (R = H, Me) in the presence of AgBF4 gives the first platinocenium dications, [Pt (eta5-C5Me5)(eta5-C5R5)]2+ (BF4-)2. On electrochemical reduction, [Pt( eta5-C5Me5)2]2+ yields [Pt(eta4-C5Me5H)(eta2-C5Me5)]+ BF4-.