ISOLATION, STRUCTURAL CHARACTERIZATION, AND DIOXYGEN REACTIVITY OF THE HETEROBIMETALLIC COMPLEX [OS(N)(CH2SIME3)2(OCRO3)(DPPE)]-

Authors
ALLEN JL SHAPLEY PA WILSON SR
Citation
Jl. Allen et al., ISOLATION, STRUCTURAL CHARACTERIZATION, AND DIOXYGEN REACTIVITY OF THE HETEROBIMETALLIC COMPLEX [OS(N)(CH2SIME3)2(OCRO3)(DPPE)]-, Organometallics, 13(10), 1994, pp. 3749-3751
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
10
Year of publication
1994
Pages
3749 - 3751
Database
ISI
SICI code
0276-7333(1994)13:10<3749:ISCADR>2.0.ZU;2-Z
Abstract
The heterobimetallic complex [Y][Os(N)(CH2-SiMe3)2(mu-O)2CrO2], 1 (Y = [PPh4], [N(n-Bu)4]), reacts with Ph2PCH2CH2PPh2 (dppe) to form [Y][Os (N)(CH2-SiMe3)2(dppe)(OCrO3)], 2. The structure of 2 was determined by X-ray diffraction. Complex 1 is a catalyst for the oxidation of dppe to Ph2P(O)CH2CH2P(O)Ph2 with molecular oxygen.