ISOMERIZATION OF (OC)5WPPH2CH2CH(PPH2)2

Authors
KEITER RL KEITER EA OLSON DM BUSH JR LIN WY BENSON JW
Citation
Rl. Keiter et al., ISOMERIZATION OF (OC)5WPPH2CH2CH(PPH2)2, Organometallics, 13(10), 1994, pp. 3752-3754
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
10
Year of publication
1994
Pages
3752 - 3754
Database
ISI
SICI code
0276-7333(1994)13:10<3752:IO(>2.0.ZU;2-P
Abstract
It has been found that (OC)5WPPh2CH2CH-(PPh2)2 (3) and (OC)5WPPh2CH(PP h2)CH2PPh2 (9) exist in equilibrium in solution at room temperature. T his isomerization is the first experimental evidence for the exchange of terminal and coordinated phosphorus groups in pentacarbonyl complex es of group 6 metals.