REACTIONS OF [CP-ASTERISK(BOOLEAN-AND)RU(OME)]2 .15. CP-ASTERISK-RU COMPLEXES OF HIGHLY FLUORINATED ARENES - MOLECULAR-STRUCTURE OF [CP(BOOLEAN-AND)RU(ETA-6-C6F5-OH)]CF3SO3 AND EXTREMELY FACILE F OH EXCHANGE IN COORDINATED FLUOROARENE LIGANDS/

Authors
KOELLE U HORNIG A ENGLERT U
Citation
U. Koelle et al., REACTIONS OF [CP-ASTERISK(BOOLEAN-AND)RU(OME)]2 .15. CP-ASTERISK-RU COMPLEXES OF HIGHLY FLUORINATED ARENES - MOLECULAR-STRUCTURE OF [CP(BOOLEAN-AND)RU(ETA-6-C6F5-OH)]CF3SO3 AND EXTREMELY FACILE F OH EXCHANGE IN COORDINATED FLUOROARENE LIGANDS/, Organometallics, 13(10), 1994, pp. 4064-4066
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
10
Year of publication
1994
Pages
4064 - 4066
Database
ISI
SICI code
0276-7333(1994)13:10<4064:RO[.CC>2.0.ZU;2-L
Abstract
Reaction of [C(p)Ru(OMe)]2 with highly fluorinated arenes gives easy access to fluoroarene CpRu sandwich complexes. The reaction is demons trated with the ligands C6F5OH and C6F6 to yield CpRu(eta6-C6F5O) (2) , [CpRu(eta6-C6F5OH)]CF3SO3 (3), and [Cp*Ru(eta6-C6F6)]CF3-SO3 (4), r espectively. [Cp AND Ru(eta6-C6F5OH)]CF3SO3 (3b) (CpAND = eta5-C5Me4Et ) crystallizes in the space group P1BAR (No. 2) with a = 9.022(2), b = 9.750(7), and c = 13.215(3) angstrom, alpha = 75.04(3), beta = 76.49( 1), and gamma = 80.34(3)-degrees, and z = 2. Extremely facile fluoride , for example, methoxide substitution, has been observed in the cation ic fluoroarene complexes.