AN UNEXPECTED REVERSAL OF STEREOCHEMISTRY IN A MODIFICATION OF THE RYCHNOVSKY CYANOHYDRIN ALKYLATION

Citation
Lj. Brzezinski et al., AN UNEXPECTED REVERSAL OF STEREOCHEMISTRY IN A MODIFICATION OF THE RYCHNOVSKY CYANOHYDRIN ALKYLATION, Tetrahedron letters, 35(41), 1994, pp. 7601-7604
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
41
Year of publication
1994
Pages
7601 - 7604
Database
ISI
SICI code
0040-4039(1994)35:41<7601:AUROSI>2.0.ZU;2-K
Abstract
Alkylation of cyanohydrin 1,3-acetonides with unsaturated substitution at the 2-position is described. The stereochemistry of the products o btained from this reaction was opposite to that anticipated.