Js. Morrill et Wm. Benesch, ROLE OF N-2(A' (5)SIGMA(G)(-PI(G)(V=10) POPULATIONS IN THE AFTERGLOW()) IN THE ENHANCEMENT OF N2B3), The Journal of chemical physics, 101(8), 1994, pp. 6529-6537
Time-resolved spectroscopic observations of the N-2 1PG afterglow, b(3
)II(g)-->A (3) Sigma(u)(+), following a pulsed discharge show both an
enhancement in the overall intensity and significant changes the shape
of bands which arise from the v = 10 level of the B (IIg)-I-3. Model
results indicated that these changes in shape are produced by an enhan
cement of the population of the low J levels Omega=2 component of the
v = 10 level. In addition, we also observed bands of the Herman Infrar
ed system of N-2 (HIR), C'' (IIu)-I-5-->A' (5) Sigma(g)(+), specifical
ly the (3,1) and (2,0) bands. During the afterglow, both the 1PG and H
IR are being produced by energy pooling processes. The time-dependent
increase of the 1PG v'= 10 band intensities show a strong correlation
with the variation in the HIR band intensities which predominately pop
ulate the lower levels of the A' (5) Sigma(g)(+). Recent work has show
n the A' (5) Sigma(g)(+) to have a significantly deeper potential well
than previously thought so that it is now thought to cross the B (IIg
)-I-3. Based on our measurements and a simple model of the afterglow w
e have estimated the apparent rate coefficient for collisional transfe
r between A' (5) Sigma(g)(+) and the high v levels of the B (IIg)-I-3
due to collisions with the N-2 ground state. The value for collisional
transfer from A' to B is approximately 1.0X10(-11) cc/molecule s. Our
observations indicate the A' (5) Sigma(g)(+) may have an even deeper
potential and we estimate an upper bound for v = 0 to be similar to 35
90+/-32 cm(-1) below the dissociation limit which is similar to 500+/-
32 cm(-1) deeper than the recent theoretical estimate.