Ms. Mikhelashvili et Eb. Krissinel, REVERSIBLE CHARGE-TRANSFER IN DIELECTRIC RESTRICTED AND FRACTAL SOLIDS - LOW CONCENTRATION OF ACCEPTORS, The Journal of chemical physics, 101(8), 1994, pp. 7169-7173
We study the influence of dielectric properties of medium with dielect
ric constant epsilon in the charge transfer processes in the restricte
d and fractal solid spaces. It is shown that this influence is determi
ned by the space restriction and its regularity. The increasing of eps
ilon promotes charge separation in restricted and fractal systems. The
fractal properties grow weakly with increasing of epsilon, its increa
sing transfers the irregular fractal space into the regular one with r
espect to the charge transfer at epsilon much greater than alpha, The
corresponding dependencies of the charge transfer efficiency on the va
lue of epsilon are presented. The space restriction and breach of its
homogeneous with alteration of epsilon give qualitatively identical re
sults. The obtained results are good for low concentration of accepter
s.