1-O-Hexadecylglycerol (chimyl alcohol), 1-O-heptadecylglycerol and 1-O
-octadecylglycerol (batyl alcohol) have been identified as the major n
ative constituents of a mixture of free alkyl glycerol ethers isolated
from the contained water and the methanolic extract of the sponge Des
mapsamma anchorata. Minor components were the free C-14, C-15, C-19, C
-20 and C-21 alkyl glycerol monoethers. The alkyl glycerol monoethers
were analyzed and identified by gas chromatography/mass spectrometry o
f their isopropylidene derivatives. This is the first report on the oc
currence of free C-15, C-19, C-20 and C-21 alkyl glycerol monoethers i
n a sponge.