Hc. Lee et al., INFLUENCES OF DEPOSITION PARAMETERS ON THE CRYSTALLOGRAPHIC ORIENTATION OF REACTIVELY SPUTTERED ALUMINUM NITRIDE THIN-FILMS, European journal of solid state and inorganic chemistry, 31(6), 1994, pp. 513-523
Aluminum nitride (AlN) thin films were fabricated on silicon and glass
substrates by reactive RF magnetron sputtering in Ar-N2 gas mixtures
without substrate heating. It is essential to control the c-axis orien
tation of AlN films with deposition parameters for the applications of
surface acoustic wave devices, since the piezoelectric properties are
strongly dependent upon the crystallographic orientation of AlN film.
The influences of sputtering pressure and nitrogen concentration on t
he crystallographic orientation are investigated employing X-ray diffr
action (XRD), stress measurement and plasma analysis. It is found that
the c-axis orientation of deposited film changes from parallel to per
pendicular with respect to the substrate surface, as sputtering pressu
re decreases and nitrogen concentration increases. The magnitude of co
mpressive stress increases with the decrease of sputtering pressure. T
he principal effect of decreasing sputtering pressure, therefore, is t
he enhancement of mean free path and adatomic mobility at the film sur
face. In addition, the cause of high c-axis orientation with the incre
ase of nitrogen concentration may be attributed to the increase of N2
and N2+ ions in the plasma, through the plasma analysis.