ADDITION-COMPOUNDS OF DICHLORODIOXOMOLYBDENUM(VI) FROM HYDROCHLORIC-ACID SOLUTIONS OF MOLYBDENUM TRIOXIDE - CRYSTAL-STRUCTURE OF DICHLORODIOXODIAQUAMOLYBDENUM(VI) BIS(2,5,8-TRIOXANONANE)

Authors
ARNAIZ FJ AGUADO R SANZAPARICIO J MARTINEZRIPOLL M
Citation
Fj. Arnaiz et al., ADDITION-COMPOUNDS OF DICHLORODIOXOMOLYBDENUM(VI) FROM HYDROCHLORIC-ACID SOLUTIONS OF MOLYBDENUM TRIOXIDE - CRYSTAL-STRUCTURE OF DICHLORODIOXODIAQUAMOLYBDENUM(VI) BIS(2,5,8-TRIOXANONANE), Polyhedron, 13(19), 1994, pp. 2745-2749
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
19
Year of publication
1994
Pages
2745 - 2749
Database
ISI
SICI code
0277-5387(1994)13:19<2745:AODFH>2.0.ZU;2-K
Abstract
The behaviour of hydrochloric acid solutions Of MoO3 with some common solvents has been explored. MoO2Cl2(H2O)2 separates from solution stab ilized as polyether solvates. The crystal structure of [MoO2Cl2(H2O)2( 2,5,8-trioxanonane)2] presents octahedral MoO2Cl2(H2O)2 Units linked t o the polyether chains through hydrogen bonds involving the water mole cules. The polyether molecules show a cis-cis conformation.