Mass-transport enhancement by rising single and multiple bubble stream
s was monitored on a vertical electrode incorporating a mosaic of 100
x 100 mum sensing elements. Limiting current measurements of the reduc
tion of ferric to ferrous sulfate revealed the presence of two distinc
t mechanisms: surface renewal is effective within a swath of five bubb
le diameters, while macroscopic laminar flows induced by rising bubble
s contribute weaker enhancement over a wider path. Enhancement caused
by a sheath of multiple side-by-side bubble streams can be well repres
ented by the linear superposition of the effect of single streams. Gen
erally, at equivalent volumetric rates, small bubbles are more effecti
ve than larger ones in reducing mass-transfer resistance to the underl
ying surface.