LIMITING CURRENT-DENSITY ON A LINE ELECTRODE IN THE PRESENCE OF TANGENTIAL, OSCILLATING FLUID-FLOW

Citation
Xd. Wang et al., LIMITING CURRENT-DENSITY ON A LINE ELECTRODE IN THE PRESENCE OF TANGENTIAL, OSCILLATING FLUID-FLOW, Journal of the Electrochemical Society, 141(10), 1994, pp. 2753-2758
Citations number
20
Categorie Soggetti
Electrochemistry
ISSN journal
00134651
Volume
141
Issue
10
Year of publication
1994
Pages
2753 - 2758
Database
ISI
SICI code
0013-4651(1994)141:10<2753:LCOALE>2.0.ZU;2-P
Abstract
Results of numerical simulations of the effect of an oscillating fluid flow on the limiting-current distribution on a line electrode imbedde d in an otherwise insulated plane are presented. The fluid motion is e stablished by a parallel plate oscillating in its own plane. The simul ation results agree with theory developed for large Peclet numbers and low oscillation frequencies. It is shown that the average mass-transf er-limited current density increases with Peclet number but decreases with dimensionless oscillation frequency. The time-averaged spatial va riation in the normalized distribution is always highly nonuniform, bu t the temporal variations of the spatially averaged flux decrease sign ificantly with increasing oscillation frequency.