K. Ljungberg et al., BURIED COBALT SILICIDE LAYERS IN SILICON CREATED BY WAFER BONDING, Journal of the Electrochemical Society, 141(10), 1994, pp. 2829-2833
A buried conductive layer in silicon has been created using wafer bond
ing technique, with a cobalt interfacial layer. Co-coated silicon wafe
rs were brought into contact with either similar or uncoated wafers at
room temperature. CoSi2 was then formed through a solid-phase reactio
n, during an anneal at 700 to 900-degrees-C. A 700 angstrom buried CoS
i2-layer, with a resistivity of approximately 21 muOMEGA cm, was achie
ved. Good adhesion, as measured by tensile strength testing, between t
he wafers was achieved. Transmission electron microscopic investigatio
ns (Co-coated wafer bonded to bare silicon) showed that the silicide h
as not grown into the opposite wafer, and that an amorphous layer exis
ts between the silicide and the silicon surface. The presence of such
a layer has been confirmed by electrical characterization.