Eu. Okoroafor et Sj. Spells, THE APPLICATION OF MIXED-CRYSTAL IR SPECTROSCOPY TO MOLECULAR DEFORMATION IN POLYETHYLENE BY ROLLING, Polymer, 35(21), 1994, pp. 4578-4589
The mixed crystal i.r. technique has been applied to polyethylene sing
le crystal mats after rolling at room temperature to roll ratios up to
6.0. Reduction in the absorbance of the outer CD2 bending components
provides evidence of lamellar breakup. Model calculations indicate tha
t the size of blocks which break away from the crystals is reduced to
approximately 36 angstrom for a ratio of 6, while X-ray diffraction da
ta show that crystallite reorientation occurs progressively with incre
asing roll ratio. Changes in small-angle X-ray scattering and the Rama
n longitudinal acoustic mode with rolling demonstrate that crystallite
stacking periodicity is gradually lost and that crystal thickness rem
ains unchanged.