Ea. Dzhavadyan et al., THE EFFECT F EXTENDERS ON PHYSICOMECHANICAL CHARACTERISTICS OF EPOXY POLYMERS AND COMPOSITES BASED ON EXTENDED POLYMERS, Vysokomolekularnye soedinenia. Seria A, 36(8), 1994, pp. 1349-1352
The effect of extenders on the properties of epoxy polymers and epoxy-
based composites was investigated. Three types of extenders were studi
ed, the reactive one, which is chemically incorporated into polymer ne
twork (diglycidyl ether of diethylene glycol), inert (dibutyl phthalat
e), and a surfactant containing double bonds and capable to polymerize
in the course of curing. All the extenders in low concentrations were
shown to improve rheological characteristics of polymer, enhance elas
tic modulus of cured polymer, yet reduce its ultimate strain and stren
gth. The inert extender causes a decrease in adhesive and tensile stre
ngth of the composites based on extended polymer, whereas reactive ext
ender and surfactant in certain concentrations not only do not affect
those but even somewhat enhance strength of composites. A possible exp
lanation based on the concept of phase separation of components in the
course of curing and modification of interphase boundary is proposed
for the effect.