An investigation has been carried out into the chemical composition of
fume produced from rosin core solder wire subjected to the heat of so
ldering. Solders containing flux based on two rosin types, Portuguese
Rosin 'Y' and American Rosin 'WW', were included and the chemical comp
ositions of the aldehydic, volatile and particulate fractions of the f
ume have been determined. Aldehydes were found to be predominantly for
maldehyde and acetaldehyde with the ratio between the two depending on
solder type and soldering temperature. The volatile terpene compositi
on of the fume varied considerably depending on the rosin and activato
r present in the solder flux. Resin acids make up the major part of th
e particulate fraction of the fume. The seven principal resin acid com
ponents were identified.