INTRAMOLECULAR INVERSION OF CONFIGURATION AT TETRAHEDRAL CARBON CENTERS IN DIPOLAR SPIRO-DELTA-COMPLEXES OF AMINOTHIOTROPONES, DIAMINOTHIOTROPONES AND AMINOTHIOTROPONES - A DYNAMIC NMR SPECTRAL STUDY

Authors
OLEKHNOVICH LP BUDARINA ZN LESIN AV KURBATOV SV BORODKIN GS MINKIN VI
Citation
Lp. Olekhnovich et al., INTRAMOLECULAR INVERSION OF CONFIGURATION AT TETRAHEDRAL CARBON CENTERS IN DIPOLAR SPIRO-DELTA-COMPLEXES OF AMINOTHIOTROPONES, DIAMINOTHIOTROPONES AND AMINOTHIOTROPONES - A DYNAMIC NMR SPECTRAL STUDY, Mendeleev communications, (5), 1994, pp. 162-164
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
5
Year of publication
1994
Pages
162 - 164
Database
ISI
SICI code
0959-9436(1994):5<162:IIOCAT>2.0.ZU;2-Q
Abstract
Inversion of configuration at the tetrahedral carbon centres of dipola r spiro-sigma-complexes formed by coupling 2-(N-benzylamino)tropone, 2 -(N-benzylamino)thiotropone or N,N'-dibenzyl-2-aminotroponimine with e lectrophilic aromatic and heterocyclic compounds has been found to occ ur intramolecularly with energy barriers accessible to measurement by means of dynamic H-1 NMR spectral techniques.