P. Thouvenot et al., SPECTROSCOPIC STUDY AND CRYSTAL-FIELD ANALYSIS OF CM3-SYMMETRY SITE OF THO2( IN THE CUBIC), Physical review. B, Condensed matter, 50(14), 1994, pp. 9715-9720
Fluorescence and excitation spectra of Cm3+ diluted in ThO2 powder are
reported at room and low temperatures. The observed Cm3+ spectra are
from the cubic symmetry lattice site and are assigned to phonon-assist
ed electric dipole transitions and to magnetic dipole transitions. Fro
m these assignments, the crystal-field parameters B-0(4) = -6436 cm-1
and B-0(6) = 1195 cm-1 have been determined. The experimental energy l
evels for the ground term (approximately 80% S-8(7/2)) determined from
the optical data and earlier electron paramagnetic resonance spectra
are in good agreement with the calculated values.