The inclusion of a detailed treatment of solidification processes in t
he cooling theory of carbon-oxygen white dwarfs is of crucial importan
ce for the determination of their luminosity function. Carbon-oxygen s
eparation at crystallization yields delays larger than 2 Gyr in the co
oling time for a white dwarf to cool down to the observed cutoff lumin
osity, i.e., log (L/L.) approximately 4.5. When calculating the lumino
sity function, this leads to estimates of the age of the Galactic disk
1.5-2 Gyr older than the ones obtained when ignoring such separation
processes. Furthermore, the presence of minor chemical species, in par
ticular, Ne-22 and Fe-56, alters significantly the crystallization pro
cess and the cooling time and produces extra delays of 2-3 Gyr. Howeve
r, the detailed computation of the theoretical white dwarf luminosity
function, takng into account galactic chemical evolution, shows that,
for minor species, this effect does not modify significantly the locat
ion of the cutoff, and thus the estimated age of the disk. The effect
of Ne-22 crystallization is shown to produce a sharp peak in the lumin
osity function at log (L/L.) approximately - 3.8. Though nondetectable
with present-day observations, this peak can be used as a future obse
rvational test of the crystallization of minor chemical species in whi
te dwarf interiors.