Through a theoretical analysis combined with new experimental data, ob
tained through a technique that allows observation of ionization origi
nating from a constant, sharply limited ion extraction volume, we show
that double multiphoton ionization of Xe and Kr in the wavelength ran
ge 527 to 531 nm does not involve an observable direct two-electron ch
annel but does involve an inner subshell (5s for Xe and 4s for Kr) exc
ited state which can leave the ion in an excited state. This explains
the unusual laser power dependence that had been attributed to a direc
t two-electron channel.