W. Soszka, LARGE-ANGLE AND SMALL-ANGLE ION-SCATTERING SPECTROSCOPY FOR STUDYING COLD, CLEAN AND GAS-COVERED METAL-SURFACES, Progress in Surface Science, 53(2-4), 1996, pp. 273-285
New possibilities of the large-angle and small-angle ion scattering sp
ectroscopy are demonstrated. If the target material consists of two or
more isotope components it was found that the ratio of isotope parts
of the quasi-single-scattering peak reaches a maximum at some incidenc
e angle. The maximum is attributed to the fact that the ions doubly sc
attered from the atoms with smaller masses can have the same energy an
d exit angle as the ions singly scattered from the atoms with larger m
asses. Based on the atomic pair model (shadowing atom plus scattering
atom) the mean distance between two atoms of the topmost atomic layer
can be found. In the range of small scattering angles the substrate qu
asi-single-scattering peak as well as the recoil peak show a fine stru
cture if the cold metal surface is covered by a thin film of condensed
gases. It is postulated that such effect is connected with a multiple
scattering of projectiles and recoils inside the condensed film. Mult
iple scattering direct the ions to the detector after single scatterin
g from the substrate atom over the angles larger Or smaller that the d
etection angle. This effect can be used for determination of a cleanli
ness of the target surface or parameters of the condensed layer (thick
ness or density).