SPECTROSCOPY OF HEXAFLUORIDES WITH AN ODD NUMBER OF ELECTRONS - OPERATORS OF INTEREST FOR ELECTRONIC SPECTROSCOPY AND FOR THE JAHN-TELLER EFFECT

Authors
BOUDON V MICHELOT F MORETBAILLY J
Citation
V. Boudon et al., SPECTROSCOPY OF HEXAFLUORIDES WITH AN ODD NUMBER OF ELECTRONS - OPERATORS OF INTEREST FOR ELECTRONIC SPECTROSCOPY AND FOR THE JAHN-TELLER EFFECT, Journal of molecular spectroscopy, 166(2), 1994, pp. 449-470
Citations number
19
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
166
Issue
2
Year of publication
1994
Pages
449 - 470
Database
ISI
SICI code
0022-2852(1994)166:2<449:SOHWAO>2.0.ZU;2-2
Abstract
A simplified model describing the electronic levels of a (f2g)n config uration is proposed. A new tensorial formulation for Jahn-Teller (line ar, quadratic,. . .) operators is developed. Particular attention is g iven to the case of electronic states with G' symmetry and to their vi bronic structures. Calculations and predictions are made for the a and e electronic states of IrF6. (C) 1994 Academic Press, Inc.