NEW TERNARY COMPOUNDS OF CESIUM AND ELEME NTS OF THE 8TH TRANSITION-METAL GROUP AND THE 5TH MAIN-GROUP

Authors
NOACK M SCHUSTER HU
Citation
M. Noack et Hu. Schuster, NEW TERNARY COMPOUNDS OF CESIUM AND ELEME NTS OF THE 8TH TRANSITION-METAL GROUP AND THE 5TH MAIN-GROUP, Zeitschrift fur anorganische und allgemeine Chemie, 620(10), 1994, pp. 1777-1780
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
10
Year of publication
1994
Pages
1777 - 1780
Database
ISI
SICI code
0044-2313(1994)620:10<1777:NTCOCA>2.0.ZU;2-V
Abstract
In the ternary systems Cesium/element of the 8th transition metal grou p/element of the 5th main group some new compounds were found and inve stigated. Compounds of the formula Cs2MX2 (M = Pt, Pd, Ni; X = P, Sb, Bi) can be placed in a line with the K2PdP2-type structure. The new co mpound with the formula CsFe2Sb2 crystallizes in the ThCr2Si2-type str ucture. By single crystal measurements CsFe2As2 was found to crystalli ze in the space group I4/mmm with the lattice constants a = 389.43 pm and c = 1509.97 pm.