M. Asbrand et B. Eisenmann, CARBONATE ISOSTRUCTURAL ANIONS [SNX3]5- I N THE COMPOUNDS RB6[SNX3]O0.5 AND CS6[SNX3]O0.5 WITH X=AS, SB, AND BI, Zeitschrift fur anorganische und allgemeine Chemie, 620(10), 1994, pp. 1837-1843
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
The metallic shining compounds Rb6[SnX3]O0.5 and Cs6[SnX3]O0.5 with X
= As, Sb, and Bi were prepared from the melt starting from adequate mi
xtures of the elements and SnO2. They crystallize in the hexagonal sys
tem (space group P6(3)/mmc, No. 194, Z = 2) with the lattice constants
mentioned in ''Inhaltsubersicht''. In the structures of the isotypic
compounds tin and the main group(V) elements build up trigonal planar
anions [SnX3]5- with X = As, Sb, and Bi isostructural to the carbonate
anion, oxygen forms isolated O2- ions. The bond lengths Sn-X are sign
ificantly shortened with respect to the sums of Pauling covalent radii
. The atoms of the units [SnX3]5- are coordinated by alkali metal cati
ons forming trigonal prisms and the O2- anions occupy octahedral holes
.