Jh. Pang et Na. Clark, OBSERVATION OF A CHIRAL-SYMMETRY-BREAKING TWIST-BEND INSTABILITY IN ACHIRAL FREELY SUSPENDED LIQUID-CRYSTAL FILMS, Physical review letters, 73(17), 1994, pp. 2332-2335
Freely suspended smectic-C films, 2, 3, and 4 layers in thickness, of
the achiral compound C7F15CH2O-phi-COO-phi-OC6H13 exhibit a thermotrop
ic transition at which the uniform two-dimensional smectic-C molecular
orientation field becomes modulated by a periodic bend wave soliton.
No such transition is found in single-layer firms. This transition is
interpreted as a chiral-symmetry-breaking transition, marking the spon
taneous appearance of frustrated local bend.