SYNTHESIS AND STRUCTURE OF A CYCLIC BISMUTH AMIDE

Citation
U. Wirringa et al., SYNTHESIS AND STRUCTURE OF A CYCLIC BISMUTH AMIDE, Inorganic chemistry, 33(21), 1994, pp. 4607-4608
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201669
Volume
33
Issue
21
Year of publication
1994
Pages
4607 - 4608
Database
ISI
SICI code
0020-1669(1994)33:21<4607:SASOAC>2.0.ZU;2-Q
Abstract
Compound 2 was prepared by a salt elimination reaction of lithiated 2, 6-diisopropylaniline with BiCl3 in 3:1 molar ratio. Single-crystal X-r ay structure analysis reveals a planar amino-substituted Bi-N ring rep resenting the first example of this type of Bi-N system. Compound 2 co mpletes the intensively investigated field of cyclic group 15 amides s uch as cyclophosphazanes, -arsazanes, and -stibazanes.