REDUCTION OF THE AMIDO-BONDED (2-PICOLINAMIDO)PENTAAMMINERUTHENIUM(III) FOLLOWED BY FORMATION OF CIS-(2-PICOLINAMIDE)TETRAAMMINERUTHENIUM(II)

Authors
DAROCHA ZN CHIERICATO G TFOUNI E
Citation
Zn. Darocha et al., REDUCTION OF THE AMIDO-BONDED (2-PICOLINAMIDO)PENTAAMMINERUTHENIUM(III) FOLLOWED BY FORMATION OF CIS-(2-PICOLINAMIDE)TETRAAMMINERUTHENIUM(II), Inorganic chemistry, 33(21), 1994, pp. 4619-4620
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
21
Year of publication
1994
Pages
4619 - 4620
Database
ISI
SICI code
0020-1669(1994)33:21<4619:ROTA(>2.0.ZU;2-R
Abstract
[(NH3)(5)Ru-III(2-NCpy)], obtained from electrochemical oxidation of t he Ru(II) complex, undergoes hydrolysis to the amido-bonded [Ru-III(NH C(O)-2-py)]. The electrochemical reduction of this latter complex to R u(II) is followed by an aquation reaction to form [R(II)(NH3)(5)(OH2)] and free picolinamide and a chelation reaction to form cis-[R(II)-(NH 3)(4)(2-pica)] with the displacement of one cis ammonia.