STUDIES ON OXIDATION OF FURAN-DERIVATIVES - MECHANISM OF 2,3-DIHYDROFURAN AND 2,5-DIHYDROFURAN OXIDATION WITH CE(IV) IN AQUEOUS-SOLUTIONS CONTAINING PERCHLORIC-ACID
M. Ignachak et al., STUDIES ON OXIDATION OF FURAN-DERIVATIVES - MECHANISM OF 2,3-DIHYDROFURAN AND 2,5-DIHYDROFURAN OXIDATION WITH CE(IV) IN AQUEOUS-SOLUTIONS CONTAINING PERCHLORIC-ACID, Izvestia vyssih ucebnyh zavedenij. Himia i himiceskaa tehnologia, 37(3), 1994, pp. 3-8
The oxidation of 2,3- and 2,5-dihydrofuran with Ce (IV) in the water s
olutions containing perchloric acid has been studied. Stoichiometric n
umbers and kinetic parameters were determined. The mechanisms of these
reactions have been proposed from the experimental data and MNDO-simu
lations.