OXIDATION OF CYCLOOCTANE DERIVATIVES WITH CE(IV) IN PERCHLORIC-ACID SOLUTIONS

Authors
Citation
Y. Dzegets, OXIDATION OF CYCLOOCTANE DERIVATIVES WITH CE(IV) IN PERCHLORIC-ACID SOLUTIONS, Izvestia vyssih ucebnyh zavedenij. Himia i himiceskaa tehnologia, 37(3), 1994, pp. 8-12
Citations number
14
Categorie Soggetti
Chemistry
ISSN journal
05792991
Volume
37
Issue
3
Year of publication
1994
Pages
8 - 12
Database
ISI
SICI code
0579-2991(1994)37:3<8:OOCDWC>2.0.ZU;2-F
Abstract
Influence of the reactants concentration on the reduction kinetics of Ce (IV) with cyclooctane, cyclooctanone and cyclooctanol has been dete rmined. Products of these compounds oxidation were isolated. The most reasonable mechanisms have been proposed from the kinetic, spectral an d chromatographic data.