DIMERIC BIS(TRIALKYLPHOSPHANE)RHODIUM CHL ORIDES - PREPARATION AND CHARACTERIZATION

Authors
BINGER P HAAS J GLASER G GODDARD R KRUGER C
Citation
P. Binger et al., DIMERIC BIS(TRIALKYLPHOSPHANE)RHODIUM CHL ORIDES - PREPARATION AND CHARACTERIZATION, Chemische Berichte, 127(10), 1994, pp. 1927-1929
Citations number
35
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
10
Year of publication
1994
Pages
1927 - 1929
Database
ISI
SICI code
0009-2940(1994)127:10<1927:DBCO-P>2.0.ZU;2-W
Abstract
High-yield methods for the preparation of (PMe3)3RhCl (2) and [(R3P)2R hCl]2 [R = Me (3a); iPr (3b), and cyclohexyl (3c)] are described. The dimeric nature of 3b in the solid state has been established by an X-r ay analysis.