HEXAKIS(ALKYLTHIO)-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES

Authors
DABAK S GUL A BEKAROGLU O
Citation
S. Dabak et al., HEXAKIS(ALKYLTHIO)-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES, Chemische Berichte, 127(10), 1994, pp. 2009-2012
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
10
Year of publication
1994
Pages
2009 - 2012
Database
ISI
SICI code
0009-2940(1994)127:10<2009:HUP>2.0.ZU;2-3
Abstract
Cyclotrimerization of 4,5-bis(hexylthio)phthalodinitrile (1) in 1-chlo ronaphthalene in the presence of BCl3 leads to the subphthalocyanine 4 . Unsymmetrical phthalocyanines (5, 6) with six alkylthio substituents on three of the benzenoid units are synthesized by the reaction of 4 with an diminoisoindoline derivative (R' = H or NO2). These extremely soluble compounds are characterized by IR, H-1- and C-13-NMR as well a s UV/Vis spectra.