REGIOSELECTIVE ATTACK OF A SOFT CARBON NUCLEOPHILE AND HYDROGEN-SULFIDE AT THE CENTRAL CARBON OF A BETA-SUBSTITUTED ETA(3)-ALLYL TO RESPECTIVELY FORM ETA(3)-TMM AND NEW METALLACYCLIC THIACYCLOBUTANE COMPLEXES

Authors
TSAI FY CHEN HW CHEN JT LEE GH WANG Y
Citation
Fy. Tsai et al., REGIOSELECTIVE ATTACK OF A SOFT CARBON NUCLEOPHILE AND HYDROGEN-SULFIDE AT THE CENTRAL CARBON OF A BETA-SUBSTITUTED ETA(3)-ALLYL TO RESPECTIVELY FORM ETA(3)-TMM AND NEW METALLACYCLIC THIACYCLOBUTANE COMPLEXES, Organometallics, 16(5), 1997, pp. 822-823
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
5
Year of publication
1997
Pages
822 - 823
Database
ISI
SICI code
0276-7333(1997)16:5<822:RAOASC>2.0.ZU;2-V
Abstract
The cationic beta-substituted allyl complexes {Pt(PPh(3))(2)[eta(3)-CH 2C(OE)CH2]}(+) (E = silyl, alkyl, acyl) undergo the substitution of th e carbon nucleophile for OE at the allyl central carbon to transform i nto eta(3)-TMM complexes or undergo addition by hydrogen sulfide to yi eld new metallathiacyclobutane complexes.