SINGLE-STEP SYNTHESES OF LACTOSYLATED CLUSTERS BY TELOMERIZATIONS

Authors
ARAVIND S PARK WKC BROCHU S ROY R
Citation
S. Aravind et al., SINGLE-STEP SYNTHESES OF LACTOSYLATED CLUSTERS BY TELOMERIZATIONS, Tetrahedron letters, 35(42), 1994, pp. 7739-7742
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
42
Year of publication
1994
Pages
7739 - 7742
Database
ISI
SICI code
0040-4039(1994)35:42<7739:SSOLCB>2.0.ZU;2-#
Abstract
N-Acryloylated lactoside derivatives containing spacer arms of differe nt length were polymerized in the presence of thiols acting as radical scavengers to provide small oligomeric clusters (telomers) in a singl e step. t-Butyl mercaptan and methyl 3-mercaptopropionate, chosen as c hain transfer reagents, were used for further attachment to L-lysine m ethyl ester.