THEORETICAL AND EXPERIMENTAL STUDIES ON THE PERISELECTIVITY OF THE CYCLOADDITION REACTION BETWEEN ACTIVATED KETENES AND CONJUGATED IMINES

Authors
ARRASTIA I ARRIETA A UGALDE JM COSSIO FP LECEA B
Citation
I. Arrastia et al., THEORETICAL AND EXPERIMENTAL STUDIES ON THE PERISELECTIVITY OF THE CYCLOADDITION REACTION BETWEEN ACTIVATED KETENES AND CONJUGATED IMINES, Tetrahedron letters, 35(42), 1994, pp. 7825-7828
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
42
Year of publication
1994
Pages
7825 - 7828
Database
ISI
SICI code
0040-4039(1994)35:42<7825:TAESOT>2.0.ZU;2-I
Abstract
Theoretical and experimental studies on the cycloaddition between meth oxyketene and a model conjugated imine predict the preferential format ion of the [2+2] cycloadduct. A configuration interaction level of the ory is required to reproduce correctly the observed periselectivity.