N. Antohe et al., AROMATIC ISOTHIOCYANATES REACTIONS WITH E PSILON-AMINO-CAPRONIC ACID ETHYLIC AND GLYCOLIC ESTER, Revista de chimie, 45(9), 1994, pp. 756-761
New thiourea derivatives were synthesized, starting from the following
aromatic isothioscyanates; phenyl isothiocyanate, o-, m-, p- tolyl is
othiocyanate, p- bromine and p- iodine phenyl isothiocyanate, with the
epsilon- amino-caprionic ethylic ester and glycolic ester, respective
ly. The compounds were characterized by elementary analysis and IR spe
ctroscopy and their structure was thus confirmed. The reactions took p
lace in a completely anhydrous medium the yields being in excess of 85
%, function of the reagents structure. The compounds obtained served a
s standard in characterizing the sulphur containing polymers got from
the epsilon- amino-caprionic acid glycolic ester, with the aromatic di
isothiocyanates.