Vi. Saloutin et al., INTERACTION OF PERFLUOROPENT-2-ENE AND ITS 2-AMINO-4-IMINO DERIVATIVEWITH ETHYLENEDIAMINE AND WITH DIETHYLENETRIAMINE, Journal of fluorine chemistry, 69(1), 1994, pp. 25-29
fluoromethyl-6-fluoro-2,3-dihydro-1H-1,4-diazepine has been prepared b
y the reaction of perfluoropent-2-ene (or 2-amino-4-iminoperfluoropent
-2-ene) with ethylenediamine. Both perfluoropent-2-ene and 2-amino-4-i
minoperfluoropent-2-ene were found to react with diethylenetriamine to
form thyl-3,4,6,7-tetrahydro-2H-pyrazino[1,2-a]pyrazine (established
by X-ray study). Some salts and the complex with BF3 of this bicyclic
compound are described.