The interaction between electrons and organized organic thin films was
investigated by measuring the energy distribution of photoelectrons i
njected from a thin sliver film coated with thin organic layers. Elect
rons with energy above similar to 0.8 eV were transmitted ballisticall
y through an organic layer that contains up to five monolayers, each s
imilar to 2 nm thick. Elastic scattering processes contribute signific
antly to the electron energy distribution only for thicker layers. The
transmission of low-energy electrons is controlled mainly by an elect
rostatic barrier perpendicular to the surface. A signature of a band s
tructure in the organic layer was observed when the electrons were tra
nsmitted through 13 layers. (C) 1997 by John Wiley & Sons, Ltd.