A USEFUL METHOD IN ORGANOTIN CHEMISTRY - DIIMINE HYDROGENATION OF 1,2-BIS(TRIMETHYLSTANNYL)-1-ALKENES, 1-TRIMETHYLSILYL-2-TRIMETHYLSTANNYL-1-ALKENES AND SOME DISTANNACYCLOPENTENES

Authors
MITCHELL TN KOWALL B
Citation
Tn. Mitchell et B. Kowall, A USEFUL METHOD IN ORGANOTIN CHEMISTRY - DIIMINE HYDROGENATION OF 1,2-BIS(TRIMETHYLSTANNYL)-1-ALKENES, 1-TRIMETHYLSILYL-2-TRIMETHYLSTANNYL-1-ALKENES AND SOME DISTANNACYCLOPENTENES, Journal of organometallic chemistry, 481(1), 1994, pp. 137-142
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
481
Issue
1
Year of publication
1994
Pages
137 - 142
Database
ISI
SICI code
0022-328X(1994)481:1<137:AUMIOC>2.0.ZU;2-O
Abstract
The title compounds can be readily hydrogenated by diimine produced in situ from commercial 80% hydrazine hydrate, 30% hydrogen peroxide and a 1% copper sulphate solution. Replacement of the methyl groups on ti n by butyl groups causes the consumption of the alkene to fall dramati cally under standard reaction conditions.