A new nonlinear optical phenomenon, biphotonic self-diffraction (BSD),
is reported in azo dye doped in polymer matrix. The first-order and t
he second-order BSD signals are observed in the experiment. It is demo
nstrated that the dynamic behaviors of the BSD signals are dependent o
n the cis-trans isomerization of azo molecules by two color lights. (C
) 1997 American Institute of Physics.